Hydrothermal Synthesis and Crystal Structure of a New Dinuclear Copper Complex: Cu2(Ophen)2·2H2O(HOphen=2-Hydroxy-1,10-Phenanthroline)
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Abstract
A new dinuclear copper complex: Cu2(Ophen)2·2H2O(HOphen=2-hydroxy1,10-phenanthroline) was hydrothermally synthesized and its structure characterized through IR spectra and single crystal X-ray diffraction analysis.Crystal data: Orthorhombic,a=(0.384 2(5) nm,) b=1.913(3) nm,c=2.691(3) nm,α=β=γ=90.00°,Z=2,V=(1.978(4) nm3,)(Dc=)(1.344 mg/m3,) R1=0.083 9,wR1=0.147 1.The ligand 2-hydroxy-1,10-phenanthroline comes from the hydroxylation of phenanthroline.There are two solvent water molecules in the compound.
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