温敏性PAC/HPMC水凝胶的制备与性能研究
Preparation and Property Study of Thermo-Sensitive PAC/HPMC Hydrogel
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摘要: 以醚-羟丙甲基纤维素(HPMC),聚阴离子纤维素(PAC)和氯化铝为原料,通过物理方法制备了一系列热缩型温敏性PAC/HPMC水凝胶,并对凝胶强度、溶胀动力学、耐盐性和温敏性进行了研究. 结果表明:PAC/HPMC水凝胶强度受到HPMC用量和相对分子质量影响. 在研究范围内,当HPMC的2.0%水溶液黏度为4Pa·s,加入量为0.10%时所制备的凝胶强度最大;与纯PAC凝胶相比,PAC/HPMC凝胶在去离子水中的平衡溶涨率有显著提高;PAC/HPMC凝胶的溶胀率随着NaCl溶液浓度的增加而减小,PAC/Abstract: A series of thermo-sensitive hydrogels were successfully prepared by physical methods with hydroxy propyl methyl callulose(HPMC), pollyanionic callulose(PAC), AlCl<sub<3</sub<·6H<sub<2</sub<O as raw materials, and their properties such as gel strength, swelling behavior,salt resistence and temperature sensibility were studied.The results showed that the gel strength of PAC/HPMC hydrogel was influenced by HPMCs content and molecular weight. There was always an optimum content and molecular weight corresponding to the maximum in gel strength. The equilibium swelling ratio of PAC/HPMC hydrogel decreased with the concentration of Nacl solution and were always higher than that of pure PAC hydrogel; PAC/HPMC hydrogels were thermosensitive, the LCST of PAC/HPMC hydrogels were lower than those of HPMC.
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