温敏性PAC/HPMC水凝胶的制备与性能研究

Preparation and Property Study of Thermo-Sensitive PAC/HPMC Hydrogel

  • 摘要: 以醚-羟丙甲基纤维素(HPMC),聚阴离子纤维素(PAC)和氯化铝为原料,通过物理方法制备了一系列热缩型温敏性PAC/HPMC水凝胶,并对凝胶强度、溶胀动力学、耐盐性和温敏性进行了研究. 结果表明:PAC/HPMC水凝胶强度受到HPMC用量和相对分子质量影响. 在研究范围内,当HPMC的2.0%水溶液黏度为4Pa·s,加入量为0.10%时所制备的凝胶强度最大;与纯PAC凝胶相比,PAC/HPMC凝胶在去离子水中的平衡溶涨率有显著提高;PAC/HPMC凝胶的溶胀率随着NaCl溶液浓度的增加而减小,PAC/

     

    Abstract: A series of thermo-sensitive hydrogels were successfully prepared by physical methods with hydroxy propyl methyl callulose(HPMC), pollyanionic callulose(PAC), AlCl<sub<3</sub<·6H<sub<2</sub<O as raw materials, and their properties such as gel strength, swelling behavior,salt resistence and temperature sensibility were studied.The results showed that the gel strength of PAC/HPMC hydrogel was influenced by HPMCs content and molecular weight. There was always an optimum content and molecular weight corresponding to the maximum in gel strength. The equilibium swelling ratio of PAC/HPMC hydrogel decreased with the concentration of Nacl solution and were always higher than that of pure PAC hydrogel; PAC/HPMC hydrogels were thermosensitive, the LCST of PAC/HPMC hydrogels were lower than those of HPMC.

     

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