高电流密度下闭式PEMFC尾排参数对性能及能量效率的影响规律

Effects of Purge Parameters on Performance and Energy Efficiency in Dead-Ended PEMFC at High Current Density Condition

  • 摘要: 针对高电流密度工况下闭式氢氧质子交换膜燃料电池(PEMFC)因液态水积累导致性能下降的问题,开展尾排参数规律及控制策略研究. 通过数值模拟的方法,获得1.5 A/cm2下不同尾排参数(吹扫触发时刻、吹扫时长以及吹扫计量比)对性能恢复以及效率的影响规律. 研究表明,吹扫计量比为2.5,吹扫时长由1 s增至3 s时,电压恢复率由99.12%增至99.88%;吹扫时长为1 s,吹扫计量比由1.5增至2.5时,能量效率由15.37%增至25.77%. 为提高能量效率,进一步提出基于水饱和度(阈值40%)的尾排控制策略,能量效率提高至37.13%,为闭式PEMFC长时稳定运行的参数优化与控制策略设计提供理论支撑.

     

    Abstract: To address performance degradation caused by liquid-water accumulation in a dead-ended proton exchange membrane fuel cell (PEMFC) at high current density, tail-purge parameter effects and control strategies were investigated. Through numerical simulations, the effects of different purge parameters at 1.5 A/cm2—including purge triggering time, purge duration, and purge stoichiometry—on voltage recovery and energy efficiency were examined. The results show that when purge stoichiometry was 2.5, increasing purge duration from 1 s to 3 s improved voltage recovery rate from 99.12% to 99.88%; when purge duration was 1 s, increasing purge stoichiometry from 1.5 to 2.5 raised energy efficiency from 15.37% to 25.77%. To further enhance energy efficiency, a water-saturation-based purge control strategy (threshold: 40%) was proposed, achieving an efficiency of 37.13%. These findings provide theoretical support for parameter optimization and control strategy development to enable long-term stable operation of dead-ended PEMFCs.

     

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